Cigarette filter butts-derived activated carbon with free binder electrode design for solid-state supercapacitor application From hazardous waste to solid-state supercapacitor
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Keywords:
cigarette filter, activated carbon monolith, activated cigarette filter carbon, KOH activation, Supercapacitor
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Abstract
The aim of this research is to formulate activated carbon monolith from hazardous waste of cigarette filter butts (CFB) for electrode material monolith design in solid-state supercapacitor application. Potassium hydroxide (KOH) was selected for activation. The ratio of CFB to KOH varied in terms of weight between 1:2 and 1:4, thereby obtaining activated cigarette filter carbon (ACFC). The carbon that has been obtained is designed to be solidly in the form of an additive-free monolith. Monolith-activated carbon is physically characterized to examine thermal decomposition profiles (pre-carbonized), structure, composition, morphology, surface area adsorption, and electrochemical measurements. The optimum precursor was marked with high wettability with self-O-doped of 5.44%.in carbon content of 94.56%. Activated carbon electrodes prepared from ACFCs showed an optimum specific capacitance of ~87.17 F g-1, which is a more ecologically responsible method of producing supercapacitors.
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Hamzah, Y., Taer, E., Apriwandi, A., Supian, F. L., Mozaffari, N., & Mozaffari, N. (2023). Cigarette filter butts-derived activated carbon with free binder electrode design for solid-state supercapacitor application: From hazardous waste to solid-state supercapacitor. Communications in Science and Technology, 8(2), 134-142. https://doi.org/10.21924/cst.8.2.2023.1252
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9. R. Li, X. Tian, M. Wei, A. Dong, X. Pan, Y. He, X. Song, H. Li, Flexible pressure sensor based on cigarette filter and highly conductive MXene sheets, Compos. Commun. 27 (2021) 100889.
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11. R. Bandi, N.P. Devulapalli, R. Dadigala, B.R. Gangapuram, V. Guttena, Facile Conversion of Toxic Cigarette Butts to N,S-Codoped Carbon Dots and Their Application in Fluorescent Film, Security Ink, Bioimaging, Sensing and Logic Gate Operation, ACS Omega. 3 (2018) 13454–13466.
12. G. Shah, U. Bhatt, V. Soni, A comprehensive review on triple R eco-management strategies to reduce, reuse and recycle of hazardous cigarette butts, Heliyon. 9 (2023) e16642.
13. M.B. d’Heni Teixeira, M.A.B. Duarte, L. Raposo Garcez, J. Camargo Rubim, T. Hofmann Gatti, P.A.Z. Suarez, Process development for cigarette butts recycling into cellulose pulp, Waste Manag. 60 (2017) 140–150.
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19. R. Bi, S.K. Pang, K.C. Yung, L.K. Yin, Comprehensive study of used cigarette filters-derived porous activated carbon for Supercapacitors: From biomass waste to sustainable energy source, J. Electroanal. Chem. 925 (2022).
20. A.M. Abioye, F.N. Ani, Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: A review, Renew. Sustain. Energy Rev. 52 (2015) 1282–1293..
21. Q. Xiong, Q. Bai, C. Li, H. Lei, C. Liu, Y. Shen, H. Uyama, Cost-effective, highly selective and environmentally friendly superhydrophobic absorbent from cigarette filters for oil spillage clean up, Polym. 10 (2018) 1101.
22. A.R. Selvaraj, A. Muthusamy, In-ho-Cho, H.J. Kim, K. Senthil, K. Prabakar, Ultrahigh surface area biomass derived 3D hierarchical porous carbon nanosheet electrodes for high energy density supercapacitors, Carbon N. Y. 174 (2021) 463–474.
23. B. Shaku, T.P. Mofokeng, N.J. Coville, K.I. Ozoemena, Biomass valorisation of marula nutshell waste into nitrogen-doped activated carbon for use in high performance supercapacitors, Electrochim. Acta. 442 (2023) 141828.
24. E. Taer, F. Febriyanti, W.S. Mustika, R. Taslim, A. Agustino, A. Apriwandi, Enhancing the performance of supercapacitor electrode from chemical activation of carbon nanofibers derived Areca catechu husk via one-stage integrated pyrolysis, Carbon Lett. (2020).
25. E. Taer, L. Pratiwi, Apriwandi, W.S. Mustika, R. Taslim, Agustino, Three-dimensional pore structure of activated carbon monolithic derived from hierarchically bamboo stem for supercapacitor application, Commun. Sci. Technol. 5 (2020) 22–30.
26. S. Saini, P. Chand, A. Joshi, Biomass derived carbon for supercapacitor applications: Review, J. Energy Storage. 39 (2021) 102646.
27. S. Majid, A.S.G. Ali, W.Q. Cao, R. Reza, Q. Ge, Biomass-derived porous carbons as supercapacitor electrodes-A review, New Carbon Mater. 36 (2021) 546–572.
28. E. Taer, Apriwandi, Windasari, R. Taslim, M. Deraman, Novel laurel aromatic evergreen biomass derived hierarchical porous carbon nanosheet as sustainable electrode for high performance symmetric supercapacitor, J. Energy Storage. 67 (2023) 107567.
29. X. Xu, L. Yang, K. Zhuo, Z. Zhang, Q. Du, C. Wang, Y. Chen, Y. Zhao, Honeysuckle flowers-derived hierarchical porous carbon matching with ionic liquid electrolyte for high-energy supercapacitors, J. Energy Storage. 41 (2021) 102988.
30. J. Serafin, M. Baca, M. Biegun, E. Mijowska, R.J. Kale?czuk, J. Sre?scek-Nazzal, B. Michalkiewicz, Direct conversion of biomass to nanoporous activated biocarbons for high CO2 adsorption and supercapacitor applications, Appl. Surf. Sci. 497 (2019) 143722.
31. S. Huo, M. Liu, L. Wu, M. Liu, M. Xu, W. Ni, Y.M. Yan, Synthesis of ultrathin and hierarchically porous carbon nanosheets based on interlayer-confined inorganic/organic coordination for high performance supercapacitors, J. Power Sources. 414 (2019) 383–392.
32. S. Liu, A. Li, Q. Han, C. Yang, H. Li, H. Xia, F. Ouyang, J. Zhou, X. Liu, Oxygen-directed porous activation of carbon nanospheres for enhanced capacitive energy storage, J. Power Sources. 483 (2021) 229223.
33. K.S.W. Sing, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure Appl. Chem. 54 (1982) 2201–2218.
34. F. Rouquerol, J. Ruoquerol, K. Sing, Adsorption by powders and porous solids: principles, methodology and applications, in: Adsorpt. by Powders Porous Solids, 1999: pp. 1–26.
35. R. Bardestani, G.S. Patience, S. Kaliaguine, Experimental methods in chemical engineering: specific surface area and pore size distribution measurements—BET, BJH, and DFT, Can. J. Chem. Eng. 97 (2019) 2781–2791.
36. E. Taer, M. Deraman, R. Taslim, Iwantono, Preparation of binderless activated carbon monolith from pre-carbonization rubber wood sawdust by controlling of carbonization and activation condition, AIP Conf. Proc. 1554 (2013) 33–37.
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