Thin film composite polyelectrolyte multilayer nanofiltration membrane fabricated using spin assisted layer by layer assembly: Application of solution diffusion film model

Main Article Content

Ahmad Alghamdi
Farid Fadhillah

Abstract

Thin Film Composite (TFC) Polyelectrolyte Multilayer (PEM) Nanofiltration (NF) membrane consisting of multilayer of Poly(diallyl dimethyl ammonium chloride) (PDAC) and Poly(sodium 4-styrenesulfonate) (PSS) deposited on  polyethersulfone (PES) support  was prepared using spin-assisted layer by layer assembly (SA-LbL). This work is an effort to discover new material having better characteristics and performance than commercial polyamide (PA) NF membrane. Two main operating conditions namely temperature and salt concentration were investigated and the effect of both on membrane performance was studied. Solution-diffusion Film Model (SDFM) membrane employing two fitting parameters i.e. membrane salt permeability (PS) and stagnant layer salt permeability PS(d), was used to explain membrane transport across the membrane. The result showed an good agreement between experimental and observed rejection rate suggests PEM membrane behaves similar to typical solution diffusion-type  composite membrane and SDFM can be used to predict the membrane performance and behavior.

Downloads

Download data is not yet available.

Article Details

How to Cite
Alghamdi, A., & Fadhillah, F. (2020). Thin film composite polyelectrolyte multilayer nanofiltration membrane fabricated using spin assisted layer by layer assembly: Application of solution diffusion film model . Communications in Science and Technology, 5(1), 10-15. https://doi.org/10.21924/cst.5.1.2020.177
Section
Articles
Author Biography

Farid Fadhillah, Al Imam Mohammad Ibn Saud Islamic University

Chemical Engineering Department, Assistant Professor

References

1. A. W. Mohammad, Y. H. Teow, W. L. Ang, Y. T. Chung, D. L. Oatley-Radcliffe, N. Hilal, Nanofiltration membranes review: Recent advances and future prospects, Desalination. 356 (2015) 226–254.
2. W. Cheng, C. Liu, T. Tong, R. Epsztein, M. Sun, R. Verduzco, et al., Selective removal of divalent cations by polyelectrolyte multilayer nanofiltration membrane: Role of polyelectrolyte charge, ion size, and ionic strength, J. Memb. Sci. 559 (2018) 98–106.

3. A. Prasannan, J. Udomsin, H. C. Tsai, C. F. Wang, J. Y. Lai, Robust underwater superoleophobic membranes with bio-inspired carrageenan/laponite multilayers for the effective removal of emulsions, metal ions, and organic dyes from wastewater, Chem. Eng. J. (2019) 123585.
4. E. te Brinke, D. M. Reurink, I. Achterhuis, J. de Grooth, W. M. de Vos, Asymmetric polyelectrolyte multilayer membranes with ultrathin separation layers for highly efficient micropollutant removal, Appl. Mater. Today. (2019) 100471.
5. D. L. Shaffer, J. R. Werber, H. Jaramillo, S. Lin, M. Elimelech, Forward osmosis: Where are we now?, Desalination. 356 (2015) 271–284.
6. G. Decher, Fuzzy nanoassemblies: Toward layered polymeric multicomposites, Science. 277 (1997) 1232–1237.
7. J. L. Stair, J. J. Harris, M. L. Bruening, Enhancement of the ion-transport selectivity of layered polyelectrolyte membranes through cross-linking and hybridization, Chem. Mater. 13 (2001) 2641–2648.
8. B. W. Stanton, J. J. Harris, M. D. Miller, M. L. Bruening, Ultrathin, Multilayered polyelectrolyte films as nanofiltration membranes, Langmuir. 19 (2003) 7038–7042.
9. R. Malaisamy, M. L. Bruening, High-flux nanofiltration membranes prepared by adsorption of multilayer polyelectrolyte membranes on polymeric supports, Langmuir. 21 (2005) 10587–10592.
10. S. U. Hong, R. Malaisamy, M. L. Bruening, Separation of fluoride from other monovalent anions using multilayer polyelectrolyte nanofiltration membranes, Langmuir. 23 (2007) 1716–1722.
11. S. U. Hong, L. Ouyang, M. L. Bruening, Recovery of phosphate using multilayer polyelectrolyte nanofiltration membranes, J. Memb. Sci. 327 (2009) 2–5.
12. J. J. Harris, J. L. Stair, M. L. Bruening, Layered polyelectrolyte films as selective, ultrathin barriers for anion transport, Chem. Mater. 12 (2000) 1941–1946.
13. L. Y. Ng, A. W. Mohammad, C. Y. Ng, C. P. Leo, R. Rohani, Development of nanofiltration membrane with high salt selectivity and performance stability using polyelectrolyte multilayers, Desalination. 351 (2014) 19–26.
14. Y. Huang, J. Sun, D. Wu, X. Feng, Layer-by-layer self-assembled chitosan/PAA nanofiltration membranes, Sep. Purif. Technol. 207 (2018) 142–150.
15. D. Wu, Y. Huang, S. Yu, D. Lawless, X. Feng, Thin film composite nanofiltration membranes assembled layer-by-layer via interfacial polymerization from polyethylenimine and trimesoyl chloride, J. Memb. Sci. 472 (2014) 141–153.
16. C. Liu, L. Shi, R. Wang, Crosslinked layer-by-layer polyelectrolyte nanofiltration hollow fiber membrane for low-pressure water softening with the presence of SO42? in feed water, J. Memb. Sci. 486 (2015) 169–176.
17. D. Menne, J. Kamp, J. Erik Wong, M. Wessling, Precise tuning of salt retention of backwashable polyelectrolyte multilayer hollow fiber nanofiltration membranes, J. Memb. Sci. 499 (2016) 396–405.
18. S. Rajesh, Y. Zhao, H. Fong, T. J. Menkhaus, Polyacrylonitrile nanofiber membranes modified with ionically crosslinked polyelectrolyte multilayers for the separation of ionic impurities, Nanoscale. 8 (2016) 18376–18389.
19. J. B. Schlenoff, S. T. Dubas, T. Farhat, Sprayed polyelectrolyte multilayers, Langmuir. 16 (2000) 9968–9969.
20. P.A. Chiarelli, M. S. Johal, J. L. Casson, J. B. Roberts, J. M. Robinson, H.L. Wang, Controlled fabrication of polyelectrolyte multilayer thin films using spin-assembly, Adv. Mater. 13 (2001) 1167–1171.
21. J. R. Kovacs, C. Liu, P. T. Hammond, Spray layer-by-layer assembled clay composite thin films as selective layers in reverse osmosis Membranes., ACS Appl. Mater. Interfaces. 7 (2015) 13375-13383
22. F. Fadhillah, A. M. Alghamdi, M. D. Alsubei, S. A. Aljlil, Synthesis of protein-fouling-resistance polyelectrolyte multilayered nanofiltration membranes through spin-assisted layer-by-layer assembly, J. King Saud Univ. - Eng. Sci. (2020).
23. L. Krasemann, B. Tieke, Selective Ion Transport across Self-Assembled Alternating Multilayers of Cationic and Anionic Polyelectrolytes, Langmuir. 16 (2000) 287–290.
24. F. Fadhillah, S. M. J. Zaidi, Z. Khan, M. M. Khaled, F. Rahman, P. T. Hammond, Development of polyelectrolyte multilayer thin film composite membrane for water desalination application, Desalination. 318 (2013) 19–24.
25. L. Pérez, I. Escudero, M. J. Arcos-Martínez, J. M. Benito, Application of the solution-diffusion-film model for the transfer of electrolytes and uncharged compounds in a nanofiltration membrane, J. Ind. Eng. Chem. 47 (2017) 368–374.
26. K. S. Spiegler, O. Kedem, Thermodynamics of hyperfiltration (reverse osmosis): criteria for efficient membranes, Desalination. 1 (1966) 311–326.
27. J. G. Wijmans, The role of permeant molar volume in the solution-diffusion model transport equations, J. Memb. Sci. 237 (2004) 39–50.
28. W. R. Bowen, H. Mukhtar, Characterisation and prediction of separation performance of nanofiltration membranes, J. Memb. Sci. 112 (1996) 263–274.
29. Y. Lanteri, P. Fievet, A. Szymczyk, Evaluation of the steric, electric, and dielectric exclusion model on the basis of salt rejection rate and membrane potential measurements, J. Colloid Interface Sci. 331 (2009) 148–155.
30. A. Yaroshchuk, X. Martínez-Lladó, L. Llenas, M. Rovira, J. de Pablo, Solution-diffusion-film model for the description of pressure-driven trans-membrane transfer of electrolyte mixtures: One dominant salt and trace ions, J. Memb. Sci. 368 (2011) 192–201.
31. K. S. Kim, K. H. Lee, K. Cho, C. E. Park, Surface modification of polysulfone ultrafiltration membrane by oxygen plasma treatment, J. Memb. Sci. 199 (2002) 135–145.
32. F. Fadhillah, S. M. Javaid Zaidi, Z. Khan, M. M. Khaled, P. T. Hammond, Reverse osmosis desalination membrane formed from weak polyelectrolytes by spin assisted layer by layer technique, Desalin. Water Treat. 34 (2011) 44–49.
33. Q. Liu, F. Lin, R. A. Hartwick, Poly(diallyldimethylammonium chloride) as a Cationic Coating for Capillary Electrophoresis, J. Chromatogr. Sci. 35 (1997) 126–130.
34. J. E. Yoo, K. S. Lee, A. Garcia, J. Tarver, E. D. Gomez, K. Baldwin, et al., Directly patternable, highly conducting polymers for broad applications in organic electronics, Proc. Natl. Acad. Sci. 107 (2010) 5712 LP-5717.
35. C. Wu, L. Zhao, Y. Zhang, pH-Responsive nanofiltration membranes based on porphyrin supramolecular self-assembly by layer-by-layer technique, RSC Adv. 7 (2017) 47397–47406.
36. R. Salcedo-Díaz, P. García-Algado, M. García-Rodríguez, J. Fernández-Sempere, F. Ruiz-Beviá, Visualization and modeling of the polarization layer in crossflow reverse osmosis in a slit-type channel, J. Memb. Sci. 456 (2014) 21–30.
37. K. Köhler, H. Möhwald, G. B. Sukhorukov, Thermal behavior of polyelectrolyte multilayer microcapsules:? 2. insight into molecular mechanisms for the PDADMAC/PSS system, J. Phys. Chem. B. 110 (2006) 24002–24010.
38. H. L. Tan, M. J. McMurdo, G. Pan, P. G. Van Patten, Temperature dependence of polyelectrolyte multilayer assembly, Langmuir. 19 (2003) 9311–9314.
39. S. T. Dubas, J. B. Schlenoff, Swelling and smoothing of polyelectrolyte multilayers by salt, Langmuir. 17 (2001) 7725–7727.