Efficient lead removal from industrial wastewater using activated carbon synthesized from wood sawdust

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Firdos Abdulla
Qusay Al-Obaidi
Maryam Al-Ameri
Mohd Shukor Salleh
M. N. Mohammed
Oday Abdullah
Faris H. Al-Ani

Abstract

The social economy's rapid expansion and unprecedented population growth are significantly contributing to environmental issues. Contamination of soil and water by heavy metals is a major environmental problem. Activated carbon synthesized from biomass possesses several qualities, including a large specific surface area, a hierarchically porous structure, robust adsorption capability, and high economic value. Wood sawdust, a plentiful agricultural by-product, was used to chemically produce activated carbon (AC). Lead removal from industrial wastewater was examined using this AC. The Langmuir and Freundlich models, along with first- and second-order kinetics, were applied for kinetic analysis. The novelty of this work lies in the combination of moderate-temperature chemical activation (600 °C) with Iraqi wood sawdust, achieving a remarkably high surface area (1477.54 m2/g) compared to most previously reported biomass-derived adsorbents. Results showed an impressive maximum adsorption capacity of 177.54 mg/g. This value compares favorably with many recently reported biomass-derived adsorbents. The boundary layer effect occurs, and the adsorption of Pb follows pseudo-second-order kinetics.

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Abdulla , F., Al-Obaidi , Q., Al-Ameri, M., Salleh, M. S., Mohammed, M. N., Abdullah, O., & Al-Ani, F. H. (2026). Efficient lead removal from industrial wastewater using activated carbon synthesized from wood sawdust. Communications in Science and Technology, 11(1), 162–168. https://doi.org/10.21924/cst.11.1.2026.1914
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References

1. D.R. Wicakso, A. Mirwan, E. Agustin, N.F. Nopembriani, I. Firdaus, M. Fadillah, Potential of silica from water treatment sludge modified with chitosan for Pb (II) and color adsorption in sasirangan waste solution, Commun. Sci. Technol. 7 (2022) 188–193.
2. A.D. N'diaye, et al., A review of biomaterial as an adsorbent: From the bibliometric literature review, the definition of dyes and adsorbent, the adsorption phenomena and isotherm models, factors affecting the adsorption process, to the use of typha species waste as adsorbent, Commun. Sci. Technol. 7 (2022) 140–153.
3. M.N. Mohammed, O.I. Abdullah, M.J. Jweeg, H.S.S. Aljibori, T.A. Abdullah, N.M. Alawi, R.T. Rasheed, F. Meharban, H.T. Hamzah, Q. Al-Obaidi, Comprehensive Review on Wastewater Treatment Using Nanoparticles: Synthesis of Iron Oxide Magnetic Nanoparticles, Publication Trends via Bibliometric Analysis, Applications, Enhanced Support Strategies, and Future Perspectives, ASEAN J. Sci. Eng. 5 (2025) 1–30.
4. F. Fu, Q. Wang, Removal of heavy metal ions from wastewaters: a review, J. Environ. Manage. 92 (2011) 407–418.
5. Q. Al-Obaidi, N.Y. Selem, M.H. Al-Dahhan, Emulsion liquid membrane (ELM) enhanced by nanoparticles and ionic liquid for extracting vanadium ions from wastewater, Environ. Sci. Pollut. Res. 31 (2024) 48576–48589.
6. A. Shahat, H.M.A. Hassan, H.M.E. Azzazy, E.A. El-Sharkawy, H.M. Abdou, M.R. Awual, Novel hierarchical composite adsorbent for selective lead (II) ions capturing from wastewater samples, Chem. Eng. J. 332 (2018) 377–386.
7. M. Miler, Š. Bavec, M. Gosar, The environmental impact of historical Pb-Zn mining waste deposits in Slovenia, J. Environ. Manage. 308 (2022) 114580.
8. D.R. Wicakso, A. Mirwan, E. Agustin, N.F. Nopembriani, I. Firdaus, M. Fadillah, Potential of silica from water treatment sludge modified with chitosan for Pb(II) and color adsorption in sasirangan waste solution, Commun. Sci. Technol. 7 (2022) 188–193.
9. R.M. Iqbal, W. Supriadi, R.Y.P. Burhan, S.D. Nurherdiana, R.E. Hidayati, S. Subaer, R. Bayuaji, H. Fansuri, Fabrication and characterization of fly ash-based geopolymer and its performance for immobilization of heavy metal cations, Commun. Sci. Technol. 7 (2022) 112–118.
10. C.O. Anıagor, M.C. Menkıtı, Relational description of an adsorption system based on isotherm, adsorption density, adsorption potential, hopping number and surface coverage, Sigma J. Eng. Nat. Sci. 38 (2020) 1073–1098.
11. Q. Al-Obaidi, D.S. Ibrahim, M.N. Mohammed, A.J. Sultan, F.H. Al-Ani, T.A. Abdullah, O.I. Abdullah, N.Y. Selem, A comprehensive analysis of the hydrogen generation technology through electrochemical water and industrial wastewater electrolysis, Pol. J. Chem. Technol. 26 (2024)
12. Q. Al-Obaidi, N.Y. Selem, O. Karai, K. Benabderazak, M. Al-Dahhan, Enhanced the simultaneous recovery/extraction of combined heavy metals of lead and vanadium from synthetic wastewater using an emulsion liquid membrane (ELM) with nanoparticles and ionic liquid, Appl. Water Sci. 15 (2025) 283
13. G.M. Kadum, S.A. Mahdy, E.H. Ali, Antimicrobial, anti-biofilm activity of zinc oxide nanoparticles on bacteria isolated from burns infection, AIP Conf. Proc. 3190 (2025) 030005.
14. Q. Al-Obaidi, M.S. Mahmoud, R. Nabil, Study of prototypes for biofuel production Extraction from biodegradation in oxygen-free environments Processing Wastewater, Sol. Energy Sustain. Dev. J. 14 (2025) 522–539.
15. S. Doyurum, A. Çelik, Pb (II) and Cd (II) removal from aqueous solutions by olive cake, J. Hazard. Mater. 138 (2006) 22–28.
16. T.A. Abdullah, Q. Al-Obaidi, T.A. Abdulla, R.T. Rasheed, K. Al-Azawi, F. Meharban, A Critical Review of the Photocatalytic Degradation of Pharmaceutical Residues by a TiO2-Based Photocatalyst, Hung. J. Ind. Chem. 51 (2023) 65–75.
17. T.A. Abdullah, H.L. Khaleel, A.W. Saeed, M.N. Mohammed, Q. Al-Obaidi, M.A. Hussein, W.A. Mhmood, R.T. Rasheed, O.I. Abdullah, Experimental Analysis of rGO-V2O5 Nanocomposites for Sustainable Water Remediation Completed with Bibliometric Analysis Toward Achieving Sustainable Development Goals (SDGs), ASEAN J. Sci. Eng. Mater. 5 (2026) 267–286.
18. Q. Al-Obaidi, M. Alabdulmuhsin, A. Tolstik, J.G. Trautman, M. Al-Dahhan, Removal of hydrocarbons of 4-Nitrophenol by emulsion liquid membrane (ELM) using magnetic Fe2O3 nanoparticles and ionic liquid, J. Water Process Eng. 39 (2021) 101729.
19. M. Sekar, V. Sakthi, S. Rengaraj, Kinetics and equilibrium adsorption study of lead(II) onto activated carbon prepared from coconut shell, J. Colloid Intersface Sci. 279 (2004) 307–313.
20. A.M. Rdhewa, I. Karim, Z.B. Mohammed, Changes in groundwater levels and its salinity (Badra Basin Iraq), IOP Conf. Ser.: Earth Environ. Sci. 1232 (2023) 012061.
21. A.M. El-Wakil, W.M. Abou El-Maaty, F.S. Awad, Removal of Lead from Aqueous Solution on Activated Carbon and Modified Activated Carbon Prepared from Dried Water Hyacinth Plant, J. Anal. Bioanal. Tech. 5 (2014) 1000216.
22. F.A. Abdulkareem, G.H. Mohamed, A.S. Resheq, Z. Bahaa, Assessment the performance of water treatment plants in Baghdad governorate using GIS, Period. Eng. Nat. Sci. 10 (2022) 228–238.
23. Ni'Mah, Lailan, Sri Rachmania Juliastuti, and Mahfud Mahfud. "One-stage microwave-assisted activated carbon preparation from Langsat peel raw material for adsorption of iron, manganese, and copper from acid mining waste." Commun. Sci. Technol. 8 (2023) 143-153.
24. H. Talib Hamzah, V. Sridevi, M. Seereddi, D.V. Suriapparao, P. Ramesh, C. Sankar Rao, R. Gautam, F. Kaka, K. Pritam, The role of solvent soaking and pretreatment temperature in microwave-assisted pyrolysis of waste tea powder: Analysis of products, synergy, pyrolysis index, and reaction mechanism, Bioresour. Technol. 363 (2022) 127913.
25. Thamer Adnan Abdullah, Qusay Al-Obaidi, Thaer A. Abdulla, Rashed T. Rasheed, Khalda Al-Azawi, and Faiza Meharban. A Critical Review of the Photocatalytic Degradation of Pharmaceutical Residues by a TiO2-Based Photocatalyst. Journal of Hungarian Journal of Industry and Chemistry. 51 (2023) 65–75.
26. Y.a.J.A. Hamadani, A.M. Salal, Z. Bahaa, L.N. Assi, A.S. Resheq, WQ assessment of water treatment plants using environmental and statistical indicators within Baghdad City, Period. Eng. Nat. Sci. 10 (2022) 427–438.
27. M.A. Ali, S.A. Mahdy, N.N. Hussein, Anticancer Properties of Titanium Dioxide (TiO2) Nanoparticles Obtained from Quercus infectoria Plant Extract, J. Nanostructures 14 (2024) 492–504.
28. M.A. Ali, S.A. Mahdy, N.N. Hussein, Synthesis of Titanium Dioxide Nanoparticles (TiO2) and Application for Reduction of Bacterial Growth, J. Nanostructures 14 (2024) 1046–1057.
29. P. Barpanda, G. Fanchini, G.G. Amatucci, Structure, surface morphology and electrochemical properties of brominated activated carbons, Carbon 49 (2011) 2538–2548.
30. F.M. Abdulla, Z.Y. Shnain, A.A. Alwasiti, M.F. Abid, N.H. Abdurahman, Photocatalysis technology for treating petroleum wastewater and the potential application of tapered bubble column (TBC): a review, Global NEST J. 26 (2024) 05681.
31. F.A. Abdulkareem, G.H. Mohamed, A.S. Resheq, Z. Bahaa, Assessment the performance of water treatment plants in Baghdad governorate using GIS, Period. Eng. Nat. Sci. 10 (2021) 228.
32. M.N. Mohammed, O.I. Abdullah, M.J. Jweeg, H.S.S. Aljibori, T.A. Abdullah, N.M. Alawi, R.T. Rasheed, F. Meharban, H.T. Hamzah, Q. Al-Obaidi, Comprehensive Review on Wastewater Treatment Using Nanoparticles: Synthesis of Iron Oxide Magnetic Nanoparticles, Publication Trends via Bibliometric Analysis, Applications, Enhanced Support Strategies, and Future Perspectives, ASEAN J. Sci. Eng. 5 (2025) 1–30.
33. Y. Wang, T. Zhang, X. Wang, Removal mechanism of lead by the composite of clinoptilolite, biochar, and Ca(OH)2 and its application in acid wastewater, Environ. Technol. Innov. 37 (2025) 104024.
34. F.C. Wu, R.L. Tseng, R.S. Juang, Characteristics of functional groups of adsorbents and their effects on the adsorption mechanism, J. Hazard. Mater. 364 (2019) 482–491.
35. T.A. Saleh, Adsorption isotherms and kinetic models: fundamentals and recent developments, Environ. Nanotechnol. Monit. Manag. 20 (2023) 10012.
36. Z. Zhang, et al., Adsorption of heavy metal ions on activated carbon prepared from agricultural wastes, Bioresour. Technol. 313 (2020) 123634.
37. G. Enaime, A. Baçaoui, A. Yaacoubi, Adsorption properties of activated carbon prepared from biomass waste, J. Environ. Chem. Eng. 8 (2020) 103146.
38. A.M. El-Wakil, W.M. Abou El-Maaty, F.S. Awad, Removal of lead from aqueous solution on activated carbon and modified activated carbon prepared from dried water hyacinth plant, J. Anal. Bioanal. Tech. 5 (2014) 1000187.
39. K. Li, Z. Zheng, Y. Li, Characterization and lead adsorption properties of activated carbons prepared from cotton stalk by one-step H3PO4 activation, J. Hazard. Mater. 181 (2010) 440–447.
40. M.A. Akl, A.G. Mostafa, M. Al-Awadhi, W.S. Al-Harwi, A.S. El-Zeny, Zinc Chloride Activated Carbon Derived from Date Pits for Efficient Biosorption of Brilliant Green: Adsorption Characteristics and Mechanism Study, Appl. Water Sci. 13 (2023) 226.
41. B. Wang, J. Lan, C. Bo, B. Gong, J. Ou, Adsorption of heavy metal onto biomass-derived activated carbon, RSC Adv. 13 (2023) 4275–4302.
42. M. Ulfa, R.F. Hanif, N.A. Sholeha, Surface chemistry and adsorption behavior of methylene blue on functionalized carbon materials: a comprehensive study, Commun. Sci. Technol. 10 (2025) 276–291.
43. J. Humadi, A.T. Nawaf, L.A. Khamees, Y.A. Abd-Alhussain, H.F. Muhsin, M.A. Ahmed, M.M. Ahmed, Development of new effective activated carbon supported alkaline adsorbent used for removal phenolic compounds, Commun. Sci. Technol. 8 (2023) 164–170.