Removal of Cr(VI) from aqueous solution by biochar derived from rice husk
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Keywords:
rice husk, biochar, reusable adsorbent, Cr(VI), adsorption
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Abstract
In this work, biochar produced from Indonesian rice husks. Then used as adsorbent of Cr(VI) in aqueous solution. The XRD pattern of biochar showed the characterization pattern at 23º (002) reflection, appearance of silicate oxide, and the carbon vibrations. The surface area and SEM morphologies confirmed that after pyrolysis treatment the surface of rice husk has changed. The surface area of biochar increased after thermal treatment. The adsorption study of Cr(VI) by biochar demonstrate 2nd-order reaction, and Langmuir isotherm models. The maximum adsorption capacity of biochar derived rice husk to adsorb Cr(VI) is 161.290 mg/g, and biochar showed the good potential as reuseable adsorbent to remove heavy metal in aqueous solution.
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Mohadi, R., Palapa, N. R., Taher, T., Siregar, P. M. S. B. N., Normah, Juleanti, N., Wijaya, A., & Lesbani, A. (2021). Removal of Cr(VI) from aqueous solution by biochar derived from rice husk. Communications in Science and Technology, 6(1), 11-17. https://doi.org/10.21924/cst.6.1.2021.293
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References
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O. Alagha, M.S. Manzar, M. Zubair, I. Anil, N.D. Mu’azu, A. Qureshi, Comparative adsorptive removal of phosphate and nitrate from wastewater using biochar-MgAl LDH nanocomposites: Coexisting anions effect and mechanistic studies, Nanomaterials 10 (2020).
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K. Selvi, S. Pattabhi, K. Kadirvelu, Removal of Cr(VI) from aqueous solution by adsorption onto activated carbon, Bioresour. Technol. 80 (2001) 87–89.
A. Sarkar, A. Ranjan, B. Paul, Synthesis, characterization and application of surface-modified biochar synthesized from rice husk, an agro-industrial waste for the removal of hexavalent chromium from drinking water at near-neutral pH, Clean Technol. Environ. Policy 21 (2019) 447–462.
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X. Zhang, L. Lv, Y. Qin, M. Xu, X. Jia, Z. Chen, Removal of aqueous Cr(VI) by a magnetic biochar derived from Melia azedarach wood, Bioresour. Technol. 256 (2018) 1–10.
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S. Aslam, A.M. Yousafzai, Chromium toxicity in fish: A review article, ~ 1483 ~ J. Entomol. Zool. Stud. 5 (2017) 1483–1488.
D. Huang et al., Cr(VI) removal from aqueous solution using biochar modified with Mg/Al-layered double hydroxide intercalated with ethylenediaminetetraacetic acid, Bioresour. Technol. 276 (2019) 127–132.
E. Malkoc, Y. Nuhoglu, Determination of kinetic and equilibrium parameters of the batch adsorption of Cr(VI) onto waste acorn of Quercus ithaburensis, Chem. Eng. Process. 46 (2007) 1020–1029.
Y. Lu, B. Jiang, L. Fang, F. Ling, J. Gao, F. Wu, X. Zhang, High performance NiFe layered double hydroxide for methyl orange dye and Cr(VI) adsorption, Chemosphere 152 (2016) 415–422.
F. Lyu, H. Yu, T. Hou, L. Yan, X. Zhang, B. Du, Efficient and fast removal of Pb 2+ and Cd 2+ from an aqueous solution using a chitosan/Mg-Al-layered double hydroxide nanocomposite, J. Colloid Interface Sci. 539 (2019) 184–193.
W. Qiu, Y. Zheng, Removal of lead, copper, nickel, cobalt, and zinc from water by a cancrinite-type zeolite synthesized from fly ash, Chem. Eng. J. 145 (2009) 483–488.
P. M. S. B. N. Siregar, N.R. Palapa, A. Wijaya, E.S. Fitri, A. Lesbani, Structural stability of ni/al layered double hydroxide supported on graphite and biochar toward adsorption of congo red, Sci. Technol. Indones. 6 (2021) 85–95.
A. S. Singha, A. Guleria, Utility of chemically modified agricultural waste okra biomass for removal of toxic heavy metal ions from aqueous solution, Eng. Agric. Environ. Food 8 (2015) 52–60.
R. Nadeem, M. N. Zafar, A. Afzal, M. A. Hanif, R. Saeed, Potential of NaOH pretreated Mangifera indica waste biomass for the mitigation of Ni(II) and Co(II) from aqueous solutions, J. Taiwan Inst. Chem. Eng. 45 (2014) 967–972.
M.J. Iqbal, F. Cecil, K. Ahmad, M. Iqbal, M. Mushtaq, M.A. Naeem, T.H. Bokhari, Kinetic study of Cr(III) and Cr(VI) biosorption using rosa damascena phytomass: A rose waste biomass, Asian J. Chem. 25 (2013) 2099–2103.
N. Kataria, V.K. Garg, Optimization of Pb (II) and Cd (II) adsorption onto ZnO nanoflowers using central composite design: isotherms and kinetics modelling, Elsevier B.V, (2018).
U. Garg, M.P. Kaur, G.K. Jawa, D. Sud, V.K. Garg, Removal of cadmium (II) from aqueous solutions by adsorption on agricultural waste biomass, J. Hazard. Mater. 154 (2008) 1149–1157.
Y. Xia et al., Enhanced adsorption of Pb(II) onto modified hydrochar: Modeling and mechanism analysis, Bioresour. Technol. 288 (2019) 1–8.
P. Gholami, L. Dinpazhoh, A. Khataee, A. Hassani, A. Bhatnagar, Facile hydrothermal synthesis of novel Fe-Cu layered double hydroxide/biochar nanocomposite with enhanced sonocatalytic activity for degradation of cefazolin sodium, J. Hazard. Mater. (2019) 120742.
E. Kulaksiz, B. Gözmen, B. Kayan, D. Kalderis, Adsorption of Malachite Green on Fe-modified biochar: Influencing factors and process optimization, Desalin. Water Treat. 74 (2017) 383–394.
A.M. Aljeboree, A.N. Alshirifi, A.F. Alkaim, Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon, Arab. J. Chem. 10 (2017) S3381–S3393.
I.M. Ríos-Badrán, I. Luzardo-Ocampo, J.F. García-Trejo, J. Santos-Cruz, C. Gutiérrez-Antonio, Production and characterization of fuel pellets from rice husk and wheat straw, Renew. Energy 145 (2020) 500–507.
S.J. Allen, G. Mckay, J.F. Porter, Adsorption isotherm models for basic dye adsorption by peat in single and binary component systems, J. Colloid Interface Sci. 280 (2004) 322–333.
B.H. Hameed, M.I. El-Khaiary, Malachite green adsorption by rattan sawdust: Isotherm, kinetic and mechanism modeling, J. Hazard. Mater. 159 (2008) 574–579.
Q. Yi et al., Thermogravimetric analysis of co-combustion of biomass and biochar, J. Therm. Anal. Calorim. 112 (2013) 1475–1479.
Y. Zhang, J. Zhao, Z. Jiang, D. Shan, Y. Lu, Biosorption of Fe(II) and Mn(II) ions from aqueous solution by rice husk ash, Biomed Res. Int. 2014 (2014).
K.Y. Foo, B.H. Hameed, Insights into the modeling of adsorption isotherm systems, Chem. Eng. J. 156 (2010) 2–10.
M.T. Tsay, F.W. Chang, Characterization of rice husk ash-supported nickel catalysts prepared by ion exchange, Appl. Catal. A Gen. 203 (2000) 15–22.
L. Leng et al., Surface characterization of rice husk bio-char produced by liquefaction and application for cationic dye (Malachite green) adsorption, Fuel 155 (2015) 77–85.
S. Chen, C. Qin, T. Wang, F. Chen, X. Li, H. Hou, M. Zhou, Study on the adsorption of dyestuffs with different properties by sludge-rice husk biochar?: Adsorption capacity , isotherm , kinetic , thermodynamics and mechanism, J. Mol. Liq. 285 (2019) 62–74.
C. Sun, T. Chen, Q. Huang, J. Wang, S. Lu, J. Yan, Enhanced adsorption for Pb(II) and Cd(II) of magnetic rice husk biochar by KMnO4 modification, Environ. Sci. Pollut. Res. 26 (2019) 8902–8913.
D.V. Cuong, N.L. Liu, V.A. Nguyen, C.H. Hou, Meso/micropore-controlled hierarchical porous carbon derived from activated biochar as a high-performance adsorbent for copper removal, Sci. Total Environ. 692 (2019) 844–853.
D. Özçimen, A. Ersoy-Meriçboyu, Removal of copper from aqueous solutions by adsorption onto chestnut shell and grapeseed activated carbons, J. Hazard. Mater. 168 (2009) 1118–1125.
K.M. Poo, E.B. Son, J.S. Chang, X. Ren, Y.J. Choi, K.J. Chae, Biochars derived from wasted marine macro-algae (Saccharina japonica and Sargassum fusiforme) and their potential for heavy metal removal in aqueous solution, J. Environ. Manage. 206 (2018) 364–372.
Y. Wu, Y. Zhang, J. Qian, X. Xin, S. Hu, S. Zhang, J. Wei, An exploratory study on low-concentration hexavalent chromium adsorption by Fe(III)-cross-linked chitosan beads, R. Soc. Open Sci. 4 (2017).
A. Lesbani, F. Asri, N.R. Palapa, T. Taher, A. Rachmat, Efficient removal of methylene blue by adsorption using composite based Ca / Al layered double hydroxide-biochar, Glob. NEST J. 22 (2020) 250–257.
W. Boulaiche, B. Hamdi, M. Trari, Removal of heavy metals by chitin: equilibrium, kinetic and thermodynamic studies, Appl. Water Sci. 9 (2019) 1–10.
L.N.H. Arakaki, V.L.S. Augusto Filha, K.S. De Sousa, F.P. Aguiar, M.G. Da Fonseca, J.G.P. Espínola, Silica gel ethyleneimine and its adsorption capacity for divalent Pb, Cd, and Hg, Thermochim. Acta 440 (2006) 176–180.
P. Saha, S. Chowdhury, S. Gupta, I. Kumar, Insight into adsorption equilibrium, kinetics and thermodynamics of Malachite Green onto clayey soil of Indian origin, Chem. Eng. J. 165 (2010) 874–882.
B.A. Fil, Isotherm, kinetic, and thermodynamic studies on the adsorption behavior of malachite green dye onto montmorillonite clay, Part. Sci. Technol. 34 (2016) 118–126.
M.R. Abukhadra, M.A. Sayed, A.M. Rabie, S.A. Ahmed, Surface decoration of diatomite by Ni/NiO nanoparticles as hybrid composite of enhanced adsorption properties for malachite green dye and hexavalent chromium, Colloids Surfaces A Physicochem. Eng. Asp. 577 (2019) 583–593.
N.T. Luyen, H.X. Linh, T.Q. Huy, Preparation of Rice Husk Biochar-Based Magnetic Nanocomposite for Effective Removal of Crystal Violet, J. Electron. Mater. 49 (2020) 1142–1149.
B.D. Park, S. Gon Wi, K. Ho Lee, A.P. Singh, T.H. Yoon, Y. Soo Kim, Characterization of anatomical features and silica distribution in rice husk using microscopic and micro-analytical techniques, Biomass and Bioenergy 25 (2003) 319–327.
K.Y. Foo, B.H. Hameed, Utilization of rice husk ash as novel adsorbent: A judicious recycling of the colloidal agricultural waste, Adv. Colloid Interface Sci. 152 (2009) 39–47.
I.J. Fernandes, D. Calheiro, A.G. Kieling, C.A.M. Moraes, T.L.A.C. Rocha, F.A. Brehm, R.C.E. Modolo, Characterization of rice husk ash produced using different biomass combustion techniques for energy, Fuel 165 (2016) 351–359.
S.M.L. Rosa, N. Rehman, M.I.G. De Miranda, S.M.B. Nachtigall, C.I.D. Bica, Chlorine-free extraction of cellulose from rice husk and whisker isolation, Carbohydr. Polym. 87 (2012) 1131–1138.
A.H. Wazir, I.U. Wazir, A.M. Wazir, Preparation and characterization of rice husk based physical activated carbon, Energy Sources, Part A Recover. Util. Environ. Eff. 00 (2020) 1–11.
N.R. Palapa, T. Taher, B.R. Rahayu, R. Mohadi, A. Rachmat, A. Lesbani, CuAl LDH/Rice Husk Biochar Composite for Enhanced Adsorptive Removal of Cationic Dye from Aqueous Solution, Bull. Chem. React. Eng. Catal. 15 (2020) 525–537.
L.T. Vlaev, I.G. Markovska, L.A. Lyubchev, Non-isothermal kinetics of pyrolysis of rice husk, Thermochim. Acta 406 (2003) 1–7.
M. Oktriyanti, N.R. Palapa, A. Lesbani, Effective Removal of Iron ( II ) from Aqueous Solution by Adsorption using Zn / Cr Layered Double Hydroxides Intercalated with Keggin Ion, J. Ecol. Eng. 21 (2020) 63–71.
O. Alagha, M.S. Manzar, M. Zubair, I. Anil, N.D. Mu’azu, A. Qureshi, Comparative adsorptive removal of phosphate and nitrate from wastewater using biochar-MgAl LDH nanocomposites: Coexisting anions effect and mechanistic studies, Nanomaterials 10 (2020).
I. Ullah, R. Nadeem, M. Iqbal, Q. Manzoor, Biosorption of chromium onto native and immobilized sugarcane bagasse waste biomass, Ecol. Eng. 60 (2013) 99–107.
M. Akram, H.N. Bhatti, M. Iqbal, S. Noreen, S. Sadaf, Biocomposite efficiency for Cr(VI) adsorption: Kinetic, equilibrium and thermodynamics studies, J. Environ. Chem. Eng. 5 (2017) 400–411.
K. Selvi, S. Pattabhi, K. Kadirvelu, Removal of Cr(VI) from aqueous solution by adsorption onto activated carbon, Bioresour. Technol. 80 (2001) 87–89.
A. Sarkar, A. Ranjan, B. Paul, Synthesis, characterization and application of surface-modified biochar synthesized from rice husk, an agro-industrial waste for the removal of hexavalent chromium from drinking water at near-neutral pH, Clean Technol. Environ. Policy 21 (2019) 447–462.
J. Ding et al., Adsorption and Reduction of Cr(VI) Together with Cr(III) Sequestration by Polyaniline Confined in Pores of Polystyrene Beads, Environ. Sci. Technol. 52 (2018) 12602–12611.
M. Inyang, B. Gao, Y. Yao, Y. Xue, A.R. Zimmerman, P. Pullammanappallil, X. Cao, Removal of heavy metals from aqueous solution by biochars derived from anaerobically digested biomass, Bioresour. Technol. 110 (2012) 50–56.